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Everything you ever wanted to know about oil . . .



In response to several postings and e-mails,
here's a repost of Ed Hackett's discourse\
on motor oil, with tables of specs for common
brands of oil.

I trust Ed approves of this repost.  He obviously
knows a great deal more about this topic than most
of us do.

Thanks, Ed.

Grant Lenahan

Multi viscosity oils are one of the great improvements in oils, but they
should be chosen wisely.  Always use a multi grade with the narrowest
span of viscosity that is appropriate for the temperatures you are going
to encounter.  The polymers can shear and burn forming deposits that can
cause ring sticking and other problems.  10W-40 and 5W-30 require a lot
of polymers(synthetics excluded) to achieve that range.  This has caused
problems in diesel engines, but fewer polymers are better for all
engines.  The wide viscosity range oils, in general, are more prone to
viscosity and thermal breakdown due to the high polymer content.

Very few manufactures recommend 10W-40 any more, and some threaten to
void warranties if it is used.  It was not included in this article for
that reason.  20W-50 is the same 30 point spread, but because it starts
with a heavier base it requires less viscosity index improvers
(polymers) to do the job.  AMSOIL can formulate their 10W-30 and 15W-40
with no viscosity index improvers but uses some in the 10W-40 and 5W-30.
Mobil 1 uses no viscosity improvers in their 5W-30, and I assume the new
10W-30.

Follow your manufacturer's recommendations as to which weights are
appropriate for your vehicle.

Viscosity Index is an empirical number indicating the rate of change in
viscosity of an oil within a given temperature range.  Higher numbers
indicate a low change, lower numbers indicate a relatively large change.
The higher the number the better.  This is one major property of an oil
that keeps your bearings happy.

These numbers can only be compared within a viscosity range.  It is not
an indication of how well the oil resists thermal breakdown.

Flash point is the temperature at which an oil gives off vapors that can
be ignited with a flame held over the oil.  The lower the flash point
the greater tendancy for the oil to suffer vaporization loss at high
temperatures and to burn off on hot cylinder walls and pistons.  The
flash point can be an indicator of the quality of the base stock used.
The higher the flash point the better.  400 F is the minimum to prevent
possible high consumption.  Flash point is in degrees F.

Pour point is 5 degrees F above the point at which a chilled oil shows
no movement at the surface for 5 seconds when inclined.  This
measurement is especially important for oils used in the winter.  A
borderline pumping temperature is given by some manufacturers.  This is
the temperature at which the oil will pump and maintain adequate oil
pressure.  This was not given by a lot of the manufacturers, but seems
to be about 20 degrees F above the pour point.  The lower the pour point
the better.  Pour point is in degrees F.

% sulfated ash is how much solid material is left when the oil burns.  A
high ash content will tend to form more sludge and deposits in the
engine.  Low ash content also seems to promote long valve life.  Look
for oils with a low ash content.

% zinc is the amount of zinc used as an extreme pressure, anti- wear
additive.  The zinc is only used when there is actual metal to metal
contact in the engine.  Hopefully the oil will do its job and this will
rarely occur, but if it does, the zinc compounds react with the metal to
prevent scuffing and wear.  A level of .11% is enough to protect an
automobile engine for the extended oil drain interval, under normal use.

Those of you with high reving, air cooled motorcycles or turbo charged
cars or bikes might want to look at the oils with the higher zinc
content.  More doesn't give you better protection, it gives you longer
protection if the rate of metal to metal contact is abnormally high.
High zinc content can lead to deposit formation and plug fouling.

The Data:

Listed alphabetically    --- indicates the data was not avaliable

Brand                      VI    Flash    Pour    %ash   %zinc

20W-50

AMSOIL                    136     482     -38     <.5     ---
Castrol GTX               122     440     -15     .85     .12
Exxon High Performance    119     419     -13     .70     .11
Havoline Formula 3        125     465     -30     1.0     ---
Kendall GT-1              129     390     -25     1.0     .16>
Pennzoil GT Perf.         120     460     -10     .9      ---
Quaker State Dlx.         155     430     -25     .9      ---
Shell Truck Guard         130     450     -15     1.0     .15
Spectro Golden 4          174     440     -35     ---     .15
Spectro Golden M.G.       174     440     -35     ---     .13
Unocal                    121     432     -11     .74     .12
Valvoline All Climate     125     430     -10     1.0     .11
Valvoline Turbo           140     440     -10     .99     .13
Valvoline Race            140     425     -10     1.2     .20

20W-40

Castrol Multi-Grade       110     440     -15     .85     .12
Quaker State              121     415     -15     .9      ---

15W-50

Chevron                   204     415     -18     .96    .11
Mobil 1                   180     430     -55     ---    ---
Mystic JT8                144     420     -20     1.7    .15

15W-40

AMSOIL                    135     460     -38     <.5     ---
Castrol                   134     415     -15     1.3     .14
Chevron Delo 400          136     421     -27     1.0     ---
Exxon XD3                 ---     417     -11     .9      .14
Exxon XD3 Extra           135     399     -11     .95     .13
Kendall GT-1              135     410     -25     1.0     .16
Mystic JT8                142     440     -20     1.7     .15
Shell Rotella w/XLA       146     410     -25     1.0     .13
Valvoline All Fleet       140     ---     -10     1.0     .15
Valvoline Turbo           140     420     -10     .99     .13

10W-30

AMSOIL                    142     480     -70     <.5     ---
Castrol GTX               140     415     -33     .85     .12
Chevron Supreme           150     401     -26     .96     .11
Exxon Superflo Hi Perf    135     392     -22     .70     .11
Exxon Superflo Supreme    133     400     -31     .85     .13
Havoline Formula 3        139     430     -30     1.0     ---
Kendall GT-1              139     390     -25     1.0     .16
Mobil 1                   ---     430     -60     ---     ---
Pennzoil PLZ Turbo        140     410     -27     1.0     ---
Quaker State              156     410     -30     .9      ---
Shell Fire and Ice        155     410     -35     .9      .12
Shell Super 2000          155     410     -35     1.0     .13
Shell Truck Guard         155     405     -35     1.0     .15
Spectro Golden M.G.       175     405     -40     ---     ---
Unocal Super              153     428     -33     .92     .12
Valvoline All Climate     130     410     -26     1.0     .11
Valvoline Turbo           135     410     -26     .99     .13
Valvoline Race            130     410     -26     1.2     .20

5W-30

AMSOIL                    168     480     -76     <.5     ---
Castrol GTX               156     400     -35     .80     .12
Chevron Supreme           202?    354     -46     .96     .11
Exxon Superflow HP        148     392     -22     .70     .11
Havoline Formula 3        158     420     -40     1.0     ---
Mobil 1                   150     430     -65     ---     ---
Mystic JT8                161     390     -25     .95     .1
Quaker State              165     405     -35     .9      ---
Shell Fire and Ice        167     405     -35     .9      .12
Unocal                    151     414     -33     .81     .12
Valvoline All Climate     135     405     -40     1.0     .11
Valvoline Turbo           158     405     -40     .99     .13

All of the oils above meet current SG/CD ratings and all vehicle
manufacture's warranty requirements in the proper viscosity.

All are "good enough", but those with the better numbers are icing on
the cake.

The more expensive synthetics;  AMSOIL, Mobil 1, and Spectro offer the
only truly significant differences, due to their superior high
temperature oxidation resistance, high film strength, very low tendancy
to form deposits, stable viscosity base, and low temperature flow
characteristics.  Synthetics are superior lubricants compared to
traditional petroleum oils.  You will have to decide if their high cost
is justifed in your application.

==================================================================

I just recieved this data from our local oil distributor.  It is
the update on the new Mobil 1 formulation and that for the new
Castrol Syntec.  They did not have the numbers for the new
Valvoline synthetics yet.  The data on the new Mobil 1 is pretty
impressive.  Based on these numbers, price, and availiability,
there is little need to look further for a synthetic oil.

The Syntec seems to be compromised by it's wide viscosity range.
Notice that the pour point is for all practical purposes, no
better than the Mobil 1 15W-50.  (actually, it's not as good)
While, meeting the viscosity parmeters, the wide range is
probably for marketing purposes.  The Mobil 1 15W-50 will pump at
-35 degrees F, which is as good as some conventinal 5W-30 oils.

Any of the ester based synthetics (AMSOIL, Mobil 1, and Syntec),
will give you the benefits that Castrol is making a big deal of
in their advertising.  The ability to cling to metal walls is due to
the polar nature of the ester base stock, not something unique to
Castrol's formulation.

The Data: (add to your current article)


Brand and Weight     VI    Flash     Pour     %ash     %zinc


Syntec   5W-50      180     437      -49      1.2      0.10

Mobil 1  5W-30      165     445      -65      ---      ---
        10W-30      160     450      -65      ---      ---
        15W-50      170     470      -55      ---      ---

Ed Hackett
wheeler.wrc.unr.edu
The Desert Research Institute
DoD #0200, WMTC, BMWRA, DIOC, Reno, NV   (702)673-7380
KotLS  KtoLE  DotD #0003

I'm not really a chemist, I'm just one of them motorsickle
sonsabitches.  __=o&o>__

900SS  K100RS  501 CAMEL